HOW TO NAME ORGANIC COMPOUNDS

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The official names of organic compounds are build of three parts:

Prefix--Parent--Suffix

The prefix describes what the substituents are, and where are they located. The parent names the longest carbon chain in the compound. The suffix describes what family (functional group) the compounds belongs to.

Here is a table of useful names for parents and substituents:

No of carbons parent name parent alkane substituent name
1 meth methane methyl
2 eth ethane ethyl
3 prop propane propyl
4 but butane butyl
5 pent pentane pentyl
6 hex hexane hexyl
7 hept heptane heptyl
8 oct octane octyl
9 non nonane nonyl
10 dec decane decyl

Organic compounds containing other functional groups are named based on the same principles, with each group having its characteristic name.  A very small selection of these names is shown in a table below, together with some commonly used names. 

Functional group Group suffix Example Common name
alkenes -ene ethene ethylene
alkynes -yne ethyne acetylene
alcohols -ol 
(replacing "e" in alkane name)
ethanol ethyl alcohol
ethers (alkyl alkyl) ether
(alkyl names as in substituent names)
diethyl ether ether
amines -amine
(added to the substituent name)
dimethylamine --
aldehydes -al
(replacing "e" in alkane name)
methanal formaldehyde
ketones -one
(replacing "e" in alkane name)
2-propanone acetone
carboxylic acids -oic acid
(replacing "e" in alkane name)
ethanoic acid acetic acid
esters alkyl -ate
(where "ate" replaces "oic" in the acid name)
ethyl ethanate ethyl acetate
amides amide
(where "amide" replaces "oic" in the acid name)
hexanamide --

 

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 Last updated 01/12/07

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